The mechanistic complexity of many of the reactions is such that even quite detailed studies over the 200 to 1000K range accessible to flash photolysis experiments may not be adequate.
The development of techniques which utilize flash photolysis studies on high-temperature gas mixtures behind reflected shock waves is promising in this regard, as demonstrated by the work of Yoshimura et al. (1992) and Michael and coworkers(Michael and Lim 1993).
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